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GCMS analysis results for sample AD27766, Jan 2002

Machine-extracted title · confidence 95%

Laboratory report documenting GCMS analysis of sample AD27766 for unknown compounds and surrogates on January 3, 2002.

NYC-WTC_000033343–000033357

Folder label: “GCMS X 11/16/01 A 12/18 - 12/20/01

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NYC 9/11 Public Portal Document

Library Search Compound Report

Data File : C:\HPCHEM\1\DATA\DEC1901\27766.D Vial: 9 Acq On : 20 Dec 2001 3:13 am Operator: GALOS Sample : gems unknown 11/16 Inst . : GC/MS Ins Mise Multiplr: 1.00 MS Integration Params: LSCINT.P

Quant Method : C:\HPCHEM\1\METHODS\NP112701.M (RTE Integrator) Title : 208 625/TCLP calibration table Library : C:\DATABASE\NBS75K.L ********************************************************************* Peak Number 6 2-Pentanone, 4-hydroxy-4-methy Concentration Rank 1

R.T. EstConc Area Relative to ISTD R.T.

7.86 4.11 ng/uL 1231730 1,4-Dichlorobenzene-d4 11.87

Hit# of 5 Tentative ID MW MolForm CAS# Qual

1 2-Pentanone, 4 - hydroxy - 4 - me t hyl - 116 C6H1202 000123-42-2 33 2 2-Pentanone, 4 -hydroxy-4 -methyl- 116 C6H1202 000123-42-2 23 3 Acetic acid, ano-, 1,1-dimethylet 141 C7H11NO2 001116-98-9 17 4 5-Hexen-2-on 98 C6H10O 000109-49-9 9 Abundance Scan 329 (7.856 min): 27766.D (-) m/ z 43.10 “100.00% 43 59 5000

101 .... —---P- 7.60 7.80__ 8.00 8.20 37, i, 53 J,...69....... 83.......... |.......................... t ' i ■ l ■ ■ • > I • ■ ■ > I > • • r | * f f I ' ' 1 1 I ' ' 1 ' I 1 1 1 1 I ' 1 1 1 I 1 1 1 ' I ‘ ' I1 1 1 1 1 ' m/z 59.10 54.18% m/z-> 10 20 30 40 50 60 70 80 90 100 110 120 130 Abundance #64274: 2-Pentanone, 4-hydroxy-4-methyl- 43

5000 59 7.60 7.80 8.00 8.20 m/z 101.05 19.30% 27 1 1 +49 m-t- — ... P. .. ।..... 101

m/z-> 10 20 30 40 50 60 70 80 90 100 110 120 130 Abundance #54275; 2-Pentanone, 4-hydroxy-4-methyl- 43

7.60 7.80 8.00 8.20 5000- m/ z 58.1.0 14.91% 59

15 31 I . 101 .. ...................... 83 ..........!.................................. 1 ■ i ' ' ■ ■ i ' ——————— m/z--> 10 20 30 40 50 60 70 80 90 100. 110 120 130 Abundance #7666: Acetic acid, cyano-, 1,1-dimethylethyl ester ) 59 7.60 7.80 8.00 8.20 m/ z 41.10 7.10% 5000 - 41

Lx 68 TT-f-m-l TTIIT TTT+7 t +—53 126 m/z-> 10 20 30 40I 50 60 70 80 90 100 110 120 130 7.60 7.80 8 0 8.20

27766.D NP112701.M Thu Dec 20 11:45:30 2001 Page 6

NYC-WTC_000033356

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