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GCMS analysis result with unknowns, Dec 2001

Machine-extracted title · confidence 100%

Analysis report for sample AD26391 indicating the presence of other unknown compounds on December 4, 2001.

NYC-WTC_000031509–000031529

Folder label: “GCMS X 11/5/01 A 12/1/01

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NYC 9/11 Public Portal Document

4 . Quantitation Report (QT Reviewed) Data File : C:\HPCHEM\1\DATA\NOV3001\26391.D Vial: 7 Acq On : 30 NOV 2001 5:41 pm Operator: GALOS Sample : gc/ms unknown 11/3 Inst : GC/MS Ins Mise 2 Multiplr: 1.00 MS Integration Params: RTEINT.P Quant Time: Dec 3 14:54 2001 Quant Results File: NP112701.RES Quant Method : C:\HPCHEM\1\METHODS\NP112701.M (RTE Integrator) Title : 208 625/TCLP calibration table Last Update : Wed Nov 28 15:33:44 2001 Response via : Initial Calibration DataAcq Meth : NP112701

Internal Standards R.T. Qlon Response Cone Units Dev(Min) 1) 1,4-Dichlorobenzene-d4 11.89 152 1537895 20.00 ng/uL -0.05 19) Naphthalene-d8 15.50 136 6062435 20.00 ng/uL -0.05 31) Acenaphthene-diO 20.7 164 2763548 20.00 ng/uL -0.05 49) Phenanthrene-diO 25.19 188 4055002 20.00 ng/uL -0.05 59) Chrysene-dl2 33.19 240 2742517 20.00 ng/uL -0.05 68) Perylene-dl2 37.28 264 2051628 20.00 ng/uL -0.05 System Monitoring Compounds 4) 2-Fluorophenol 0.00 112 0 0.00 ng/uL Spiked Amount 75.000 Range 18 42 Recovery = 0.00%# 5) Phenol-d5 11.21 99 3533 0.03 ng/uL 0.08 Spiked Amount 75.000 Range 19 32 Recovery = 0.04%# 6) 2-Chlorophenol-d4 11.89 132 1529 0.01 ng/uL 0.47 Spiked Amount 75.000 Range 34 84 Recovery = 0.01%# 7) 1,2-Dichlorobenzene-d4 12.40 152 15828 0.24 ng/uL -0.05 Spiked Amount 50.000 Range 26 73 Recovery = 0.48%# 20) Nitrobenzene-d5 0.00 82 0 0.00 ng/uL Spiked Amount 50.000 Range 55 98 Recovery = 0.00%# 32) 2-Fluorobiphenyl 18.92 172 5270 0.03 ng/uL 0.09 Spiked Amount 50.000 Range 42 78 Recovery = 0.06%# 33) 2,4,6-Tribromophenol 0.00 330 0 0.00 ng/uL Spiked Amount 75.000 Range 45 96 Recovery = 0.00%# 62) Terphenyl-dl4 0.00 244 0 0.00 ng/uL Spiked Amount 50.000 Range 58 98 Recovery = 0.00%# Target Coinpounds Qvalue 2) Pyridine 0.00 79 0 N.D. 3) N-nitrosodimethylamine 0.00 74 0 N.D. 8) Phenol 11.15 94 356 N.D. 9) bis(2-Chloroethyl)ether 0.00 93 0 N.D. 10) 2-Chlorophenol 0.00 128 0 N.D. 11) 1,3-Dichlorobenzene 0.00 146 0 N.D. 12) 1,4-Dichlorobenzene 0.00 146 0 N.D. 13) 1,2-Dichlorobenzene 0.00 146 0 N.D. 14) 2-Methylphenol 0.00 108 0 N.D. 15) 2,21-oxybis(1-Chloropropan 12.89 45 1880 N.D. 16) 3&4-Methylphenol 0.00 108 0 N.D. 17) N-Nitrosodi-n-propylamine 0.00 70 0 N.D. 18) Hexachloroethane 0.00 117 0 N.D. 21) Nitrobenzene 0.00 77 0 N.D. 22) Isophorone 0.00 82 0 N.D. (#) = qualifier out of range (m) = manual integration 26391.D NP112701.M Tue Dec 04 08:23:15 2001 Page 1

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