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GC/MS results for unknown compounds and surrogates, sample AE10980, May

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Laboratory report showing GC/MS analysis of sample AE10980 with surrogate recovery data for 2,4-DDD.

NYC-WTC_000023887–000023903

Folder label: “GCMS X 5/10/02 A 5/14/02

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NYC 9/11 Public Portal Document Library search Compound Report Data File : C:\MSDCHEM\l\DATA\051402\10980.D Vial: 9 Acq On : 14 May 2002 8:01 pm Operator: Mclean Sample : 5/10 kb Inst : Instrumen Mise Multiplr: 1.00 MS Integration Params: LSCINT.e Quant Method : C:\MSDCHEM\1\METHODS\050102.M (Chemstation Integrator) Title : 508 Modified GC/MS scan Library : C:\DATABASE\NIST98.L Peak Number 2 Methylene Chloride Concentration Rank 4

R.T. EstConc Area Relative to ISTD R.T.

3.73 0.44 ug/L 345108 1,4-Dichlorobenzene-d4 9.93

Hit# of 5 Tentative ID MW MolForm CAS# Q

1 Methylene Chloride 84 CH2C12 000075-09-2/90 2 Methylene Chloride 84 CH2C12 000075-09-2 90 3 Methylene Chloride 84 CH2C12 000075-09-2 90 4 Methylene Chloride 84 CH2C12 000075-09-2 10 Abundance Scan 110 (3.725 min): 10980.D (-96) (-) m/z 43.10 100.00% 43 49 84 5000

+ m 238 59 3.40 3.60 3.80 4.00 — 88 o - m/z 49.10 75.12% m/z-> 5 10 15 20 25 30 35 40 45 50 55 60 65 70 75 80 85 90 95 Abundance #111040: Methylene Chloride 49 84

5000 3.40 3.60 3.80 4.00 35 m/z 84.00 57.62% 14 88 2528 32 3841 m/z~> 5 0 THHpp TT ! >2 70 TIWWIWmPuapt 10 15 20 25 30 35 40 45 50 55 60 . 65 70 75 80 85 90 95 —mm Abundance #111039: Methylene Chloride 49 84 3.40 3.60 3.80 4.00 ' 5000 m/z 51.05 33.32%

2831 3538 43 |, Ot —————————— 152 57 67 71 77 1—umumTt 88 ilyonsipa Mnuwsr"Wwbwaoy miz-> 5 10 15 20 25 30 35 40 45 50 55 60 65 70 75 80 85 90 95 Abundance #12327: Methylene Chloride 49 3.40 3.60 3.80 4.00 84 m/z 86.00 27.66% 5000 "MAuyMuM 88

rn/z-> 14 18 24 2831 353841 0 TTTTTTTHTTTTTTTTTTTTTTTTHTTTT +2 70 T41/11111A41111128d/12A111B 5 10 15 20 25 30 35 40 45 50 55 60 65 70 75 80 85 90 95 - 3.40 3.60 3.80 4.00

10980.D 050102.M Thu May 16 14:36:22 2002 Page 5

NYC-WTC_000023896

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NYC-WTC_000023896Source: NYC Law Department, mirrored locally

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