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GCMS calibration table for TCLP extraction method

Machine-extracted title · confidence 90%

GCMS analysis results for sample AE11603 dated June 4, 2002, documenting unknown compounds and surrogate recovery.

NYC-WTC_000013968–000013996

Folder label: “GCMS X 5/24/02 A 5/28/02

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NYC 9/11 Public Portal Document Library search compound. Report Data File : C:\MSDCHEM\l\DATA\052802\11603.D ' Vial: 9 Acq On : 28 May 2002 8:49 pm Operator: McLean Sample : 5/24 ad re-ext Inst : Instrumen Mise Multiplr: 1.00 MS Integration Params: LSCINT.e Quant Method : C:\MSDCHEM\1\METHODS\052202.M (Chemstation Integrator) Title : 508 Modified GC/MS scan ** Library : C: \DATABASE\NIST98 . L ********************************************************************* Peak Number 14 Methylene Chloride Concentration Rank 19 R.T. EstConc Area Relative to ISTD R.T.

5.38 0.24 ug/L 171682 1,4-Dichlorobenzene-d4 9.90

Hit# of 5 Tentative ID MW MolForm CAS# Qual

1 Methylene Chloride 84 CH2C12 000075-09-2/4 2 2,3-Dichloropropionitrile 123 C3H3C12N 002601-89-0 4 3 Methylene Chloride 84 CH2C12 000075-09/2 2 4 Chloroiodomethane 176 CH2C1I 000593-71-5 2 Abundance Scan 391 (5.377 min): 11603.D (-388) (-) m/ z 35.10 00.00% 35 49 "MM hrw AWW 5000 207 86

m/z-> 0- । Abundance 0 । , 20 u 40 60 80 100 120 #111040: Methylene Chloride 140 160 180 200 • i • 1 ■ 1 i 5.00 m/z 5.20 49.10 ‘ i ■ ' ■ 1 i ■ 1 ' 1 1 1 5.40 5.60 63.77% 5.80

43 84

5000 5 00 5.20 5.40 ‘ ‘ 5.60 “ 5.80 35 m/z 43.10 30.85%

miz--> 0- 0 14 25 I ■ 412 ' 20 +—40 70 < > i • > ■ ‘ • 11

60 80 * ' 100 ‘ 120 ‘ 140 ' 160 ' 180 2807 Abundance #12329:2,3-Dichloropropionitrile 43 88

5.00 5.20 5.40 5.60 5.80 5000 m/z 207.00 28.57% 26 62 | 74 miz-> 0- 4.14,.37,1 L f'I 44 rfnnmDmmmmTBTGTTT 123 0 20 40 60 80 100 120 140 160 180 200 Abundance #111041: Methylene Chloride 43 500 5.20 5.40 5.60 5.80 m/z 48.00 27.12% 84 5000 MMMHmioata, 0 aan1 t 59 TP— 29 73 . r i >- •- j -I m/z—> 0 20 40 60 80 100"1120 1140’1180’180’200 5.00 5.20 5.40 5.60 5.80

11603.D 052202.M Thu May 30 10:38:55 2002 Page 17

NYC-WTC_000013989

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NYC-WTC_000013989Source: NYC Law Department, mirrored locally

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