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GCMS analysis report sample AE09678, May 23, 2002

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GCMS laboratory report for sample AE09678 detecting unknown compounds and 2,4-DDD on May 23, 2002.

NYC-WTC_000013191–000013216

Folder label: “GCMS X 5/21/02 A 5/21/02

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NYC 9/11 Public Portal Document quditlLatlOI KepOLt (VI Kevlewed) Data File : C:\MSDCHEM\1\DATA\052102\9678.D Vial: 16 Acq On : 22 May 2002 1:33 am Operator: Mclean Sample : re-extract Inst : Instrumen Mise Multiplr: 1.00 MS Integration Params: EVENTS.E Quant Time: May 22 11:34:41 2002 Quant Results File: 052202.RES Quant Method : C:\MSDCHEM\1\METHODS\052202.M (Chemstation Integrator) X Title : 508 Modified GC/MS scan / Last Update : Wed May 22 11:26:33 2002 yY Response via : Initial Calibration DataAcq Meth : 508SCAN Internal Standards R.T. Qlon Response Cone Units Dev(Min) 1) 1,4-Dichlorobenzene-d4 9.90 152 3915793 40.00 ug/L 0.00 10) Napthalene-d8 13.39 136 15432599 40.00 ug/L -0.01 17) Acenapthalene-dlO 18.53 164 8561526 40.00 ug/L -0.01 29) Phenanthranene-dlO 22.91 188 12834759 40.00 ug/L 0.00 37) Chrysene-dl2 30.76 240 7901351 40.00 ug/L -0.05 43) Perylene-dl2 34.66 264 3856621 40.00 ug/L -0.03 System Monitoring Compounds 27) TCMX 20.50 209 1706401 43.19 ug/L ’ .00 Spiked Amount 40.000 Recovery £ 107.97%

Target Compounds (value 2) n-nitros-dimethyl amine 0.00 74 0 N.D. 3) bis(2-Chloroethyl)ether 0.00 93 0 N.D. 4) 1,3-Dichlorobenzene 0.00 146 0 N.D. 5) 1,4-Dichlorobenzene 0.00 146 0 N.D. 6) 1,2-Dichlorobenzene 0.00 146 0 N.D. 7) 2,2'oxybi s(1-Chloropropane 0.00 45 0 N.D. 8) N-nitroso-di-propylamine 0.00 70 0 N.D. 9) Hexachloroethane 0.00 117 0 N.D. 11) Nitrobenzene 0.00 77 0 N.D. 12) 1sophorone 0.00 82 0 N.D. 13) bis(2-Chloroethoxy) methan 0.00 93 0 N.D. 14) 1,2,4-Trichlorobenzene 0.00 180 0 N.D. 15) Napthalene •0.00 128 0 N.D. 16) Hexachlorobutadiene 0.00 225 0 N.D. 18) 2-Chloronaphthalene 0.00 162 0 N.D. 19) Dimethylphthalate 0.00 163 0 N.D. 20) 2,6-Dinitrotoluene 0.00 165 0 N.D. 21) Ac enapt hylene 0.00 152 0 N.D. , 22) Acenapthalene 0.00 153 0 N.D. 23) 2,4-Dinitrotoluene 0.00 165 0 N.D. 24) Diethylphthalate 20.10 149 37744 N.D. 25) 4-Chlorophenyl-phenylether 0.00 204 0 N.D. 26) Fluorene 0.00 166 0 N.D. 28) Azobenzene 20.50 77 30248 N.D. 30) Nnitrosodiphenylamine 20.51 169 31670 N.D. 31) 4-Bromophenyl-phenylether 0.00 248 0 N.D. 32) Hexachlorobenzene 0.00 284 0 N.D. 33) Phenanthrene 0.00 178 0 N.D. 34) Anthracene 0.00 178 0 N.D. 35) Di-n-butylphthalate 25.05 149 260863 0.68 ug/L 97 (#) = qualifier out of range (m) = manual integration 9678.D 052202.M Wed May 22 11:34:55 2002 Page 1

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