GCMS reference standard analysis results, May 22, 2002

NYC 9/11 Public Portal Document

Quantitation Report (QT Reviewed)

Data File : C:\HPCHEM\1\DATA\MAY21O2\REF1.D Vial: 4 Acq On : 22 May 2002 4:22 am Operator: Sample : EXTRACTS/20 Inst : 209 Miso Multiplr: 1.00 MS Integration Params: GOOFY.P Quant Time: May 22 13:38 2002 Quant Results File: GCMS0520.RES Quant Method : C:\HPCHEM\1\METHODS\GCMS0520.M (RTE Integrator) Title : 209 625/TCLP calibration table Last Update : Wed May 22 09:03:22 2002 Response via : Initial Calibration DataAcq Meth : GCMS0520

Internal Standards R.T. Qlon Response Cone Units Dev(Min) 1) 1,4-Dichlorobenzene-d4 12.14 152 369159 40.00 ug/1 0.00 10) Naphthalene-d8 15.78 136 1459758 40.00 ug/1 -0.01 17) Acenaphthene-diO 21.08 164 698679 40.00 ug/1 -0.01 30) Phenanthrene-diO 25.52 188 913440 40.00 ug/1 -0.01 38) Chrysene-dl2 33.58 240 526801 40.00 ug/1 -0.03 44) Perylene-dl2 37.78 264 338393 40.00 ug/1 -0.02 System Monitoring Compounds 28) TCMX 23.22 209 136968 39.01 ug/L -0.01 Spiked Amount 40.000 Recovery 97.52% Target Compounds Qvalue 2) N-nitrosodimethylamine 5.79 74 132590 11.96 ug/1 93 3) bis(2-Chloroethyl)ether 11.54 93 264254 18.00 ug/1 97 4) 1,3-Dichlorobenzene 12.04 146 187341 15.77 ug/1 96 5) 1,4-Dichlorobenzene 12.19 146 199090 15.29 ug/1 97 6) 1,2-Dichlorobenzene 12.70 146 195523 17.34 ug/1 98 7) 2,2'-oxybi s(1-Chioropropan 13.02 45 595662 17.94 ug/1 98 8) N-Nitrosodi-n-propylamine 13.41 70 186206 17.86 ug/1 97 9) Hexachloroethane 13.55 117 65494 11.78 ug/1 # 82 11) Nitrobenzene 13.82 77 231476 18.25 ug/1 96 12) 1sophorone 14.47 82 518813 20.65 ug/1 99 13) bis(2-Chloroethoxy)methane 15.16 93 317721 18.87 ug/1 99 14) 1,2,4-Trichlorobenzene 15.66 180 150256 16.48 ug/1 98 15) Naphthalene 15.83 128 656985 19.93 ug/1 99 16) Hexachlorobutadiene 16.38 225 52242 11.84 ug/1 98 18) Hexachiorocyclopentadiene 18.57 237 11645 4.11 ug/1 96 19) 2-Chloronaphthalene 19.33 162 329083 21.13 ug/1 95 20) Dimethylphthalate 20.43 163 392018 20.00 ug/1 100 21) 2,6-Dinitrotoluene 20.65 165 73608 18.04 ug/1 89 2 2) Acenaphthylene 20.61 152 520626 18.25 ug/1 100 23) Acenaphthene 21.18 153 352342 20.67 ug/1 99 24) 2,4-Dinitrotoluene 21.81 165 85397 19.09 ug/1 94 25) Diethylphthalate 22.57 149 401704 22.18 ug/1 97 26) 4-Chlorophenylphenylether 22.72 204 165334 18.26 ug/1 95 27) Fluorene 22.69 166 356657 20.64 ug/1 100 29) Azobenzene 23.18 77 468631 17.96 ug/L 97 31) N-Nitrosodiphenylamine 23.11 168 119962 19.93 ug/1 97 32) 4-Bromophenylphenylether 24.18 248 88342 18.53 ug/1 95 3 3) Hexachlorobenzene 24.61 284 100797 19.70 ug/1 # 89 34) Phenanthrene 25.58 178 456105 20.71 ug/1 100 (#) = qualifier out of range (m) = manual integration REFl.D GCMS0520.M Wed May 22 13:39:58 2002 Page 1

NYC-WTC_0000 12667