GCMS reference analysis report, sample AE04337, March 27, 2002

NYC 9/11 Public Portal Document Quantitation Report (Not Reviewed)

.Data File : C:\MSDCHEM\1\DATA\032602\REF1B326.D Vial: 27 Acq On : 27 Mar 2002 2:45 am Operator: McLean Sample : REF 1 3/1/02 Inst : Instrumen Mise Multiplr: 1.00 MS Integration Params: BENZO.P Quant Time: Mar 27 09:02:26 2002 Quant Results File: 5080302.RES

Quant Method : C:\MSDCHEM\l\5973N\5080302.M (RTE Integrator) Title : Quantitation For Method 508gcscan Last Update : Wed Mar 27 06:57:36 2002 Response via : Initial Calibration DataAcq Meth : 508SCAN

Internal Standards R.T. Qlon Response Cone Units Dev(Min)

1) l,4-Dichlorobenzene-d4 9.55 150 1443732 20.00 ug/L 0.00 10) Naphthalene-d8 13.03 136 3951742 20.00 ug/L 0.00 17) Acenaphthene-diO 18.14 164 2156862 20.00 ug/L 0.00 29) Phenanthrene-diO 22.50 188 3025146 20.00 ug/L 0.00 38) Chrysene-dl2 30.31 240 2394224 20.00 ug/L -0.01 44) Perylene-dl2 34.18 264 1321194 20.00 ug/L 0.00

System Monitoring Compounds 37) 2,4-DDD (SURR) 27.43 235 187914 5.21 ug/L 0.00 Spiked Amount 5.000 Recovery = 104.20%

Target Compounds Qvalue 2) N-nitroso-dimethyl amine 3.59 74 152676 4.71 ug/L # 100 3) bis(2-chloroethyl) ether 8.98 93 486071 9.51 ug/L 87 4) 1,3 - Dichlorobenze 9.38 146 277362 5.49 ug/L 99 5) 1,4 - Dichlorobenzene 9.60 146 291710 5.79 ug/L 100 6) 1,2 - Dichlorobenzene 9.97 146 313877 6.73 ug/L 99 7) 2,2 ‘ - oxybis (l-Chloropr 10.43 45 1198992 10.30 ug/L 99 8) N-Nitroso-di-n-propylamine 10.75 70 413519 11.25 ug/L 97 9) Hexachloroethane 10.86 117 71712 3.79 ug/L 92 11) Nitrobenzene 11.11 77 527811 7.42 ug/L 99 12) Isophorone 11.82 82 1275853 9.74 ug/L 100 13) bis(2-Chloroethoxy) methan 12.56 93 618162 7.84 ug/L 99 14) 1,2,4-Trichlorobenzene 12.90 180 260710 5.76 ug/L 99 15) Naphthalene 13.08 128 1306058 7.95 ug/L 100 16) Hexachlorobutadiene 13.53 225 41637 1.65 ug/L 95 18) Hexachlorocyclopentadiene 15.60 237 16998 0.90 ug/L 73 19) 2-chloronaphthalene 16.50 162 661250 6.72 ug/L 97 20) Dimethylphthalate 17.59 163 998319 8.49 ug/L 99 21) 2,6-Dinitrotoluene 17.70 165 161271 6.45 ug/L 98 22) Acenaphthylene 17.69 152 1195058 8.75 ug/L 98 23) Acenaphthene 18.23 153 797188 8.58 ug/L 99 24) 2,4-Dinitrotoluene 18.86 165 212348 5.93 ug/L 95 25) Diethylphthalate 19.72 149 987422 9.76 ug/L 99 26) 4-Chlorophenyl-phenyl ethe 19.90 204 420240 7.80 ug/L 96 27) Fluorene 19.76 166 965363 8.82 ug/L 98 28) Azobenzen/ 1,2-Diphenylhyd 20.34 77 1265438 8.48 ug/L 98 30) N-Nitrosodiphenylamine 20.27 169 568786 8.75 ug/L 97 31) 4-Bromophenyl-phenyl ether 21.32 248 236181 8.84 ug/L 91 32) Hexachlorobenzene 21.35 284 229330 8.14 ug/L 97 33) Phenanthrene 22.56 178 1272642 9.08 ug/L 99 34) Anthracene 22.71 178 1159409 8.34 ug/L 98 35) Di-n-butylphthalate 24.65 149 1675211 10.43 ug/L 99 36) Fluoranthene 26.06 202 1357250 8.52 ug/L 96 39) Pyrene 26.69 202 1390812 8.40 ug/L 98 4 0) Butylbenzylphthalate 29.05 149 586268 8.27 ug/L 92 41) Benzo (a) antracene 30.28 228 1006202 8.01 ug/L 99 42) Bis (2-ethylhexyl) phthala 30.92 149 770068 8.22 ug/L 100 43) Chrysene 30.38 228 1096306 9.18 ug/L 99 45) Di-n-Octylphthalate 32.76 149 995759 7.02 ug/L 98 46) Benzo (b) fluoranthene 33.23 252 751576 8.07 ug/L 98

(#) = qualifier out of range (m) = manual integration REF1B326.D 5080302.M Wed Mar 27 09:02:55 2002 Page 1

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