GCMS calibration results, Method 508, Mar 2002

NYC 9/11 Public Portal Document

Quantitation Report (QT Reviewed)

• Data File : C:\MSDCHEM\l\DATA\031902\301REF2.D Vial: 19 Acq On : 20 Mar 2002 4:01 am Operator: McLean Sample : RE-INJ 3/1 Inst : Instrumen Mise Multiplr: 1.00 MS Integration Params: BENZO.P Quant Time: Mar 21 06:22:07 2002 Quant Results File: 5080302.RES

Quant Method : C:\MSDCHEM\1\5973N\5080302.M (RTE Integrator) Title : Quantitation For Method 508gcscan Last Update : Thu Mar 14 13:02:27 2002 Response via : Initial Calibration DataAcq Meth : 508SCAN Internal Standards R.T. Qlon Response Cone Units Dev(Min)

1) 1,4-Dichlorobenzene-d4 9.54 150 1375145 20.00 ug/L 0.00 10) Naphthalene-d8 13.03 136 3619246 20.00 ug/L 0.00 17) Acenaphthene-diO 18.13 164 2021190 20.00 ug/L 0.00 29) Phenanthrene-diO 22.50 188 3149857 20.00 ug/L 0.00 38) Chrysene-dl2 30.30 240 2826987 20.00 ug/L -0.02 44) Perylene-dl2 34.18 264 1498463 20.00 ug/L 0.00

System Monitoring Compounds 37) 2,4-ddd surr 27.43 235 172646 4.59 ug/L 0.00 Spiked Amount 5.000 Recovery = 91.80%

Target Compounds Qvalue 2) N-nitroso-dimethyl amine 3.61 74 93191 3.02 ug/L 100 3) bis(2-chloroethyl) ether 8.98 93 280333 5.76 ug/L 80 4) 1,3 - Dichlorobenze 9.39 146 197654 4.11 ug/L 98 5) 1,4 - Dichlorobenzene 9.59 146 216016 4.50 ug/L 98 6) 1,2 - Dichlorobenzene 9.97 146 215657 4.85 ug/L 96 7) 2,2 ‘ - oxybis (l-Chloropr 10.43 45 699061 6.30 ug/L 98 8) N-Nitroso-di-n-propylamine 10.75 70 218947 6.26 ug/L 99 9) Hexachloroethane 10.86 117 62442 3.46 ug/L 92 11) Nitrobenzene 11.10 77 275399 4.23 ug/L 97 12) Isophorone 11.81 82 763655 6.37 ug/L 99 13) bis(2-Chloroethoxy) methan 12.55 93 359694 4.98 ug/L 98 14) 1,2,4-Trichlorobenzene 12.90 180 182934 4.41 ug/L 98 15) Naphthalene 13.08 128 839546 5.58 ug/L 99 16) Hexachlorobutadiene 13.53 225 67552 2.92 ug/L 97 18) Hexachlorocyclopentadiene 15.61 237 24180 1.36 ug/L 96 19) 2-chloronaphthalene 16.51 162 446747 4.84 ug/L 99 20) Dimethylphthalate 17.59 163 817783 7.43 ug/L 98 21) 2,6-Dinitrotoluene 17.70 165 128986 5.50 ug/L 97 22) Acenaphthylene 17.69 152 844174 6.59 ug/L 99 23) Acenaphthene 18.22 153 583153 6.70 ug/L 99 24) 2,4-Dinitrotoluene 18.85 165 169547 5.05 ug/L 98 25) Diethylphthalate 19.72 149 773408 8.16 ug/L 98 26) 4-Chlorophenyl-phenyl ethe 19.89 204 349840 6.93 ug/L 97 27) Fluorene 19.76 166 765033 7.46 ug/L 97 28) Azobenzen/ 1,2-Diphenylhyd 20.34 77 876005 6.27 ug/L 99 30) N-Nitrosodiphenylamine 20.26 169 277899 4.10 ug/L 92 31) 4-Bromophenyl-phenyl ether 21.32 248 204111 7.34 ug/L 93 32) Hexachlorobenzene 21.34 284 214128 7.30 ug/L 94 33) Phenanthrene 22.56 178 1106372 7.58 ug/L 98 34) Anthracene 22.70 178 985361 6.81 ug/L 100 35) Di-n-butylphthalate 24.65 149. 1326950 7.94 ug/L 99 36) Fluoranthene 26.06 202 1283659 7.74 ug/L 98 39) Pyrene 26.69 202 1355661 6.94 ug/L 97 4 0) Butylbenzylphthalate 29.04 149 538216 6.43 ug/L 97 41) Benzo (a) antracene 30.29 228 1016978 6.85 ug/L 99 42) Bis (2-ethylhexyl) phthala 30.91 149 705199 6.38 ug/L 96 43) Chrysene 30.38 228 1147197 8.14 ug/L 99 45) Di-n-Octylphthalate 32.75 149 893891 5.55 ug/L 99 46) Benzo (b) fluoranthene 33.23 252 762359 7.22 ug/L 98

(#) = qualifier out of range (m) = manual integration 301REF2.D 5080302.M Thu Mar 21 06:22:31 2002 Page 1

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