GCMS Calibration Results, Sample AE01639, Mar 2002

NYC 9/11 Public Portal Document

Quantitation Report (Not Reviewed)

.♦ Pata File C:\MSDCHEM\1\DATA\031902 \CAL4OX.D Vial: 5 Acq On 19 Mar 2002 2:57 pm / Operator: McLean Sample Inst : Instrumen Mise Multiplr: 1.00 MS Integration Params: BENZO.P Quant Time: Mar 20 05:45:38 2002 Quant Results File: 5080302.RES

Quant Method : C:\MSDCHEM\l\5973N\5080302.M (RTE Integrator) Title : Quantitation For Method 508gcscan Last Update : Thu Mar 14 13:02:27 2002 Response via : Initial Calibration DataAcq Meth : 508SCAN

Internal Standards R.T. Qlon Response Cone Units Dev(Min)

1) 1,4-Dichlorobenzene-d4 9.55 150 1632058 20.00 ug/L 0.00 10) Naphthalene-d8 13.04 136 3759822 20.00 ug/L 0.00 17) Acenaphthene-diO 18.14 164 2013504 20.00 ug/L 0.00 29) Phenanthrene-diO 22.50 188 3350723 20.00 ug/L 0.00 38) Chrysene-dl2 30.33 240 2957454 20.00 ug/L 0.00 44) Perylene-dl2 34.19 264 1783164 20.00 ug/L 0.00

System Monitoring Compounds 37) 2,4-ddd surr 27.42 235 27704 0.69 ug/L 0.00 Spiked Amount 5.000 Recovery = 13.80%

Target Compounds 1-57 Qvalue 2) N-nitroso-dimethyl amine 3.55 74 1397953 38.14 ug/L 100 3) bis(2-chloroethyl) ether 9.00 93 2168309 37.53 ug/L 98 4) 1,3 - Dichlorobenze 9.39 146 2185175 38.24 ug/L 98 5) 1,4 - Dichlorobenzene 9.60 146 2168027 38.04 ug/L 99 6) 1,2 - Dichlorobenzene 9.97 146 2024068 38.37 ug/L 98 7) 2,2 ' - oxybis (l-Chloropr 10.44 45 5088133 38.66 ug/L 98 8) N-Nitroso-di-n-propylamine 10.79 70 1646102 39.62 ug/L 98 9) Hexachloroethane 10.87 117 868653 40.58 ug/L 100 11) Nitrobenzene 11.13 77 2589524 38.24 ug/L 97 12) Isophorone 11.85 82 4714138 37.83 ug/L 99 13) bis(2-Chloroethoxy) methan 12.58 93 2861315 38.16 ug/L 99 14) 1,2,4-Trichlorobenzene 12.91 180 1696456 39.41 ug/L 99 15) Naphthalene 13.10 128 6047831 38.70 ug/L 99 16) Hexachlorobutadiene 13.54 225 980447 40.73 ug/L 97 18) Hexachlorocyclopentadiene 15.61 237 756390 42.66 ug/L 98 19) 2-chloronaphthalene 16.53 162 3619965 39.38 ug/L 99 20) Dimethylphthalate 17.62 163 4294577 39.14 ug/L 99 21) 2,6-Dinitrotoluene 17.72 165 917751 39.30 ug/L 99 22) Acenaphthylene 17.71 152 4948515 38.81 ug/L 100 23) Acenaphthene 18.24 153 3390585 39.11 ug/L 99 24) 2,4-Dinitrotoluene 18.89 165 1336923 39.98 ug/L 99 25) Diethylphthalate 19.76 149 3831274 40.58 ug/L 99 26) 4-Chlorophenyl-phenyl ethe 19.91 204 1969360 39.14 ug/L 99 27) Fluorene 19.77 166 4020979 39.34 ug/L 99 2 8) Azobenzen/ 1,2-Diphenylhyd 20.37 77 5416300 38.89 ug/L 99 30) N-Nitrosodiphenylamine 20.29 169 2742929 38.09 ug/L 99 31) 4 -Bromophenyl -phenyl ether 21.33 248 1145239 38.72 ug/L 98 32) Hexachforobenzene 21.36 284 1193608 38.26 ug/L 98 33) Phenanthrene 22.58 178 5899963 38.02 ug/L 99 34) Anthracene 22.73 178 5919149 38.44 ug/L 100 35) Di-n-butylphthalate 24.66 149 6972170 39.20 ug/L 100 36) Fluoranthene 26.08 202 6976251 39.56 ug/L 99 39) Pyrene | 26.71 202 7152954 34.99 ug/L 94 4 0) Butylbenzylphthalate 29.06 149 3172876 36.24 ug/L 95 41) Benzo (a) antracene 30.31 228 5876909 37.86 ug/L 98 42) Bis (2-ethylhexyl) phthala 30.92 149 4153328 35.89 ug/L 98 43) Chrysene 30.40 228 5665892 38.42 ug/L 99 45) Di-n-Octylphthalate 32.76 149 6907981 36.07 ug/L 99 46) Benzo (b) fluoranthene 33.25 252 4887438 38.89 ug/L 99

(#) = qualifier out of range (m) = manual integration CAL40X.D 5080302.M Thu Mar 21 07:25:23 2002 Page 1

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