GCMS calibration data for Method 508, Mar 11-14 2002

NYC 9/11 Public Portal Document Quantitation Report (Not Reviewed)

‘Data File : C:\MSDCHEM\1\DATA\031102\CCKA0311.D Vial: 10 Acq On : 11 Mar 2002 7:00 pm Operator: McLean Sample : CAL CK STD Inst : Instrumen Mise Multiplr: 1.00 MS Integration Params: BENZO.P Quant Time: Mar 14 12:32:16 2002 Quant Results File: 5080302.RES

Quant Method : C:\MSDCHEM\l\5973N\5080302.M (RTE Integrator) Title : Quantitation For Method 508gcscan Last Update : Wed Mar 13 06:26:00 2002 Response via : Initial Calibration DataAcq Meth : 508SCAN

Internal Standards R.T. Qlon Response Cone Units Dev(Min)

1) 1,4-Dichlorobenzene-d4 9.54 150 1841662 20.00 ug/L 0.00 10) Naphthalene-d8 13.04 136 4460168 20.00 ug/L 0.00 17) Acenaphthene-dl0 18.14 164 2377774 20.00 ug/L 0.00 29) Phenanthrene-diO 22.50 188 3916211 20.00 ug/L 0.00 38) Chrysene-dl2 30.33 240 3406514 20.00 ug/L 0.00 44) Perylene-dl2 34.19 264 1771296 20.00 ug/L 0.00

System Monitoring Compounds 37) 2,4-ddd surr 0.00 235 0 0.00 ug/L Spiked Amount 5.000 Recovery = 0.00%

Target Compounds 2) N-nitroso-dimethyl amine 3.55 74 976342 7.5 3l. bvalue100 23.61 ug/L 3) bis(2-chloroethyl) ether 8.98 93 1641384 25.18 ug/L 97 4) 1,3 - Dichlorobenze 9.38 146 1548324 24.01 ug/L 99 5) 1,4 - Dichlorobenzene 9.59 146 1551424 24.13 ug/L 98 6) 1,2 - Dichlorobenzene 9.97 146 1479637 24.86 ug/L 98 7) 2,2 ' - oxybis (l-Chloropr 10.44 45 3536487 23.81 ug/L 97 8) N-Nitroso-di-n-propylamine 10.78 70 1239053 26.43 ug/L 99 9) Hexachloroethane 10.86 117 612483 25.35 ug/L 98 11) Nitrobenzene 11.11 77 1792715 22.32 ug/L 97 12) Isophorone 11.84 82 3377416 22.85 ug/L 99 13) bis(2-Chloroethoxy) methan 12.57 93 2016774 22.67 ug/L 100 14) 1,2,4-Trichlorobenzene 12.91 180 1189931 23.30 ug/L 98 15) Naphthalene 13.09 128 4286120 23.12 ug/L 100 16) Hexachlorobutadiene 13.53 225 685577 24.01 ug/L 96 18) Hexachlorocyclopentadiene 15.61 237 472319 22.56 ug/L 97 19) 2-chloronaphthalene 16.52 162 2626758 24.20 ug/L 99 20) Dimethylphthalate 17.62 163 3062047 23.63 ug/L 99 21) 2,6-Dinitrotoluene 17.72 165 657315 23.84 ug/L 93 2 2) Acenaphthylene 17.71 152 3617768 24.02 ug/L 100 2 3) Acenaphthene 18.24 153 2439928 23.83 ug/L 99 24) 2,4-Dinitrotoluene 18.88 165 977397 24.75 ug/L 96 25) Diethylphthalate 19.75 149 2797262 25.09 ug/L 99 26) 4-Chlorophenyl-phenyl ethe 19.90 204 1445314 24.32 ug/L 97 27) Fluorene 19.77 166 2914365 24.15 ug/L 99 28) Azobenzen/ 1,2-Diphenylhyd 20.35 77 3624151 22.04 ug/L 100 30) N-Nitrosodiphenylamine 20.28 169 2125925 25.26 ug/L 99 31) 4-Bromophenyl-phenyl ether 21.33 248 818146 23.67 ug/L 95 32) Hexachlorobenzene 21.36 284 844773 23.17 ug/L 92 33) Phenanthrene 22.58 178 4181316 23.05 ug/L 99 34) Anthracene 22.72 178 4171456 23.18 ug/L 99 35) Di-n-butylphthalate 24.66 149 5005348 24.08 ug/L 99 36) Fluoranthene 26.07 202 4772749 23.16 ug/L 99 39) Pyrene 26.70 202 4982181 21.16 ug/L 95 40) Butylbenzylphthalate 29.06 149 2211074 21.93 ug/L 98 41) Benzo (a) antracene 30.30 228 4078795 22.81 ug/L 99 42) Bis (2-ethylhexyl) phthala 30.92 149 3010415 22.58 ug/L 97 43) Chrysene 30.40 228 3846501 22.64 ug/L 99 45) Di-n-Octylphthalate 32.76 149 4728383 24.85 ug/L 99 46) Benzo (b) fluoranthene 33.24 252 3124856 25.03 ug/L 99

(#) = qualifier out of range (m) = manual integration CCKA0311.D 5080302.M Fri Mar 15 15:17:02 2002 Page 1

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