GCMS reference data, Feb 12, 2002

NYC 9/11 Public Portal Document

Quantitation Report (QT Reviewed)

File : C:\HPCHEM\1\DATA\FEB1102\REFB.D Viale 31 On : 12 Feb 2002 5:19 pm Operator: 209 GALOS aple : GC/MS SCAN 1/14 Inst :GC/MS 209 isc : Multiplr: : 1.00 MS Integration Params: GOOFY.P Quant Time: Feb 19 15:30 2002 (Quant Results File: GCMS0208.RES

Quant Method : C:\HPCHEM\1\METHODS\GCMS0208.M (RTE Integrator) Title : 209 625/TCLP calibration table Last Update : Fri Feb 08 15:29:22 2002 Response via : Initial Calibration DataAcq Meth : GCMS0208

Internal Standards R.T. Qlon Response Cone Units Dev(Min)

1) 1,4-Dichlorobenzene-d4 12.35 152 291725 20.00 ug/1 0.00 10) Naphthalene-d8 15.99 136 1121279 20.00 ug/1 0.00 17) Acenaphthene-diO 21.31 164 600459 20.00 ug/1 0.00 29) Phenanthrene-diO 25.75 188 881397 20.00 ug/1 -0.01 38) Chrysene-dl2 33.83 240 621525 20.00 ug/1 -0.01 44) Perylene-dl2 38.11 264 387490 20.00 ug/1 -0 01

System Monitoring Compounds 37) 2,4-DDD 30.84 235 54638 4.99 ug/mL 0.34 Spiked Amount 5.000 Recovery = 99.80%

Target Compounds Qvalue 2) N-nitroso-dimethyl amine 5.97 74 22512 1.93 ug/1 100 3) bis(2-Chloroethyl)ether 11.73 93 54387 2.84 ug/1 99 4) 1,3-Dichlorobenzene 12.25 146 34792 1.52 ug/1 97 5) 1,4 -Dichlorobenzene 12.39 146 38372m 1.65 ug/1 6) 1,2-Dichlorobenzene 12.91 146 39127 1.77 ug/1 98 7) 2,2' - oxybi s (l -Chloropropan 13.22 45 86494 2.98 ug/1 98 8) N-Nitroso-di-n-propylamine 13.61 70 41406 3.02 ug/1 98 9) Hexachloroethane 13.76 117 8835 0.95 ug/1 93 11) Nitrobenzene 14.03 77 57023 2.47 ug/1 98 12) Isophorone 14.68 82 115474 2.96 ug/1 100 13) bis(2-Chloroethoxy)methane 15.36 ' 93 67079 2.77 ug/1 100 14) 1,2,4-Trichlorobenzene 15.87 180 34464 1.80 ug/1 98 15) Naphthalene 16.05 128 147832 2.48 ug/1 100 16) Hexachlorobutadiene 16.59 225 10067 0.88 ug/1 99 18) Hexachlorocyclopentadiene 18.79 237 2127 N.D. 19) 2-Chloronaphthalene 19.56 162 91216 2.55 ug/1 99 20) Dimethylphthalate 20.64 163 143076 3.43 ug/1 99 21) 2,6-Dinitrotoluene 20.86 165 21097 2.23 ug/1 95 22) Acenaphthylene 20.83 152 137717 2.66 ug/1 99 23) Acenaphthene 21.40 153 104750 2.90 ug/1 96 24) 2,4-Dinitrotoluene 22.03 165 28177 2.35 ug/1 97 25) Diethylphthalate 22.78 149 147299 3.40 ug/1 100 26) 4-Chlorophenyl-phenylether 22.93 204 56394 3.02 ug/1 97 27) Fluorene 22.92 166 116495 2.95 ug/1 98 28) Azobenzen/ 1,2-Diphenylhyd 23.40 77 135496 2.97 ug/L 98

(#) = qualifier out of range (m) = manual integration REFB.D GCMS0208.M Tue Feb 19 15:32:18 2002 Page 1

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