GCMS quality control note for sample AE03016, March 2002

NYC 9/11 Public Portal Document

Data File C:\MSDCHEM\l\DATA\022802\03016.D Vial: 9 Afq On 1 Mar 2002 6:56 pm Operator: McLean Sample 2/12/02 GC SCAN Inst Instrumen Mise Multiplr: 1.00 MS Integration Params: BENZO.P Quant Time: Mar 04 05:40:36 2002 Quant Results File: 5080202.RES

Quant Method : C:\MSDCHEM\l\5973N\5080202.M (RTE Integrator) Title : Quantitation For Method 508gcscan Last Update : Mon Feb 25 19:17:14 2002 Response via : Initial Calibration DataAcq Meth : 508SCAN

Internal Standards R.T. Qlon Response Cone Units Dev(Min)

1) 1,4-Dichlorobenzene-d4 9.58 150 1451022 20.00 ug/L 0.00 10) Naphthalene-d8 13.05 136 3868061 20.00 ug/L 0.00 17) Acenaphthene-dlO 18.16 164 2146836 20.00 ug/L 0.00 29) Phenanthrene-diO 22.52 188 3336989 20.00 ug/L 0.00 38) Chrysene-dl2 30.33 240 3106407 20.00 ug/L -0.03 44) Perylene-dl2 34.21 264 2040749 20.00 ug/L 0.00

System Monitoring Compounds 37) 2,4-ddd surr 27.46 235 181462 3.43 ug/L 0.00 Spiked Amount 5.000 Recovery =/ 68.60% )

Target Compounds Qvalue 2) N-nitroso-dimethyl amine 0.00 74 0 N.D. 3) bis(2-chloroethyl) ether 0.00 93 0 N.D. 4) 1,3 - Dichlorobenze 0.00 146 0 N.D. 5) 1,4 - Dichlorobenzene 0.00 146 0 N.D. 6) 1,2 - Dichlorobenzene 0.00 146 0 N.D. 7) 2,2 ' - oxybis (l-Chloropr 0.00 45 0 N.D. 8) N-Nitroso-di-n-propylamine 0.00 70 0 N.D. 9) Hexachloroethane 0.00 117 0 N.D. 11) Nitrobenzene 0.00 77 0 N.D. 12) Isophorone 0.00 82 0 N.D. 13) bis(2-Chloroethoxy) methan 0.00 93 0 N.D. 14) 1,2,4-Trichlorobenzene 0.00 180 0 N.D. 15) Naphthalene 0.00 128 0 N.D. 16) Hexachlorobutadiene 0.00 225 0 N.D. 18) Hexachlorocyclopentadiene 0.00 237 0 N.D. 19) 2-chloronaphthalene 0.00 162 0 N.D. 20) Dimethylphthalate 0.00 163 0 N.D. 21) 2,6-Dinitrotoluene 0.00 165 0 N.D. d 22) Acenaphthylene 0.00 152 0 N.D. 23) Acenaphthene 0.00 153 0 N.D. 24) 2,4-Dinitrotoluene 0.00 165 0 N.D. 25) Diethylphthalate 0.00 149 0 N.D. 26) 4-Chlorophenyl-phenyl ethe 0.00 204 0 N.D. 27) Fluorene 0.00 166 0 N.D. 28) Azobenzen/ 1,2-Diphenylhyd 0.00 77 0 N.D. 30) N-Nitrosodiphenylamine 0.00 169 0 N.D. 31) 4-Bromophenyl-phenyl ether 0.00 248 0 N.D. 32) Hexachlorobenzene 0.00 284 0 N.D. 33) Phenanthrene 0.00 178 0 N.D. 34) Anthracene 0.00 178 0 N.D. 35) Di-n-butylphthalate 0.00 149 0 N.D. d 36) Fluoranthene 0.00 202 0 N.D. 3 9) Pyrene 0.00 202 0 N.D. 40) Butylbenzylphthalate 0.00 149 0 N.D. 41) Benzo (a) antracene’ 0.00 228 0 N.D. d 42) Bis (2-ethylhexyl) phthala 30.94 149 3927 0.03 ug/L 73 43) Chrysene 30.34 228 8723 0.04 ug/L 58 45) Di-n-Octylphthalate 0.00 149 0 N.D. 46) Benzo (b) fluoranthene 0.00 252 0 N.D.

(#) = qualifier out of range (m) = manual integration 03016.D 5080202.M Mon Mar 04 05:41:09 2002 Page 1

NYC-WTC_000005994