GCMS surrogate recovery results, sample AE03018, March 2002

NYC 9/11 Public Portal Document

Library Search Compound Report

Data File C:\MSDCHEM\l\DATA\022802\03017.D Vial: 10 Acq On 1 Mar 2002 7:45 pm Operator: McLean Sample 2/12/02 GC SCAN Inst : Instrumen Mise Multiplr: 1.00 MS Integration Params: LSCINT.P

Quant Method : C:\MSDCHEM\1\5973N\5080202.M (RTE Integrator) Title : Quantitation For Method 508gcscan Library : C:\DATABASE\WILEY7N.L ********************************************************************* Peak Number 1 3-Pentanol, 3-methyl- Concentration Rank 1

R.T. EstConc Area Relative to ISTD R.T.

5.60 1.39 ug/L 436594 1,4-Dichlorobenzene-d4 9.58

Hit# of 5 Tentative ID MW MolForm CAS# Qual

1 3-Pentanol, 3-methyl- 102 C6H14O 000077-74-7 9 2 3-Pentanol, 3-methyl- 102 C6H140 _000077-74-7 9 3 Butane, 2-methoxy-2-methyl- 102 C6H140 000994-05-8 9 4 3 -(CYCLOHEX-3'-EN-YL)PROPANOL $$. . . 174 C8H14Q 015745-87-6 9 Abundance Scan 278 (5.598 min): 03017.D (-) m/z 73.10 100.00% 73 8000

6000

4000 .................................... .................. — 1 , ,

2000 45 5.20 5.40 5.60 5.80 6.00 ............. 156. + —Tm ' I ' ' ' ' I 1 ' 1 1 I ' ' ' 1 I ' 1 ' ' I ‘ ' I ’ 87 103 m/z 45.10 14.02% m/z-> 10 20 30 40 50 60 70 80 90 100 110 Abundance #9665: 3-Pentanol, 3-methyl- 73 8000

6000

4000

2000 43 55 87 i ' 1 ■ ' i ' ' 5.20 5.40 5.60 5.80 6.00 m/z 71.10 7.59% 1 ■ ■ ( ■ ■

29

m/z-> ..................... Ill 361 , . ■ ■i■■■■I 1■ ’ 1 i ■ ■ 1 'I1 1 ' 10 20 30 40 50 -467 60 70 —Pmmm 80 90 100 110 Abundance #9663: 3-Pentanol, 3-methyl- 73 8000 T 5.20 5.40 5.60 5.80 6.00 6000 m/z 55.10 4.63% 4000 55 2000 45 87 15 27 |. I 39I I । 1। 67, ■11 ■1 1 1 i1 ■ ■ ■ i' 1 ■ ■ i ■ ।' ■ । ■ '। ■1 •' i1 ■ ■ I ' 1,1 I ’ ' 1 1 I ’ 1 ' 1 1 1 m/z-> 10 20 30 40 50 60 70 80 90 100 110 Abundance #9701: Butane, 2-methoxy-2-methyl- 73 i ' ' 1 ' i T’r 5.20 5.40 5.60 5.80 6.00 8000: m/z 74.10 4.43%

6000

4000 55 43 87 2000: 27 .41,23.11,1,49, 1 ' 1 1 ' 1 ' i ' +616741 alyunit PPI 101 i ' 1 ' ' I ' ' m/z-> 10 20 30 40 50 60 70 80 90 100 110 5.20 5.40 5.60 5.80 6.00

03017.D 5080202.M Mon Mar 04 05:42:04 2002 Page 3

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