VOCs GC/MS analysis results, Jan 3-4 2002

NYC 9/11 Public Portal Document

Quantitation Report (Not Reviewed)

Data File : C:\HPCHEM\1\DATA\02jan03\0103C10.D Vial: 2 Acq On 3 Jan 2002 9:19 am Operator: 206-bh Sample : cal 10 Inst : GC/MS Ins Misc Multiplr: 1.00 MS Integration Params: LSCINT.P Quant Time: Jan 3 9:58 2002 Quant Results File: HP121001.RES

Quant Method : C:\HPCHEM\1\METHODS\HP121001.M (RTE Integrator) Title : VOCs BY EPA METHOD 524 Last Update : Thu Dec 20 09:38:26 2001 Response via : Initial Calibration DataAcq Meth : HP121001

Internal Standards R.T. Qlon Response Conc Units Dev(Min) ------------------------------------------------------------------------- 1) 1,4-DIFLUOROBENZENE 14.39 114 707547 5.00 ug/L 0.03 22) CHLOROBENZENE-D5 20.98 117 718689 5.00 ug/L 0.02 50) 1,4-DICHLOROBENZENE-D4 26.14 152 549726 5.00 ug/L 0.03

System Monitoring Compounds 2) 1,2-DICHLOROETHANE-D4 13.60 65 253432 5.44 ug/L 1.02 Spiked Amount 5.000 Recovery = 108.80% 3) 4-BROMOFLUOROBENZENE 23.55 174 322834 5.95 ug/L f.02 Spiked Amount 5.000 Recovery = 119.00% 23) TOLUENE-D8 17.71 98 910548 4.78 ug/L 0.03 Spiked Amount 5.000 Recovery = 95.606 a

Target Compounds Qvalue 4) DICHLORODIFLUOROMETHANE 4.45 85 310838 13.46 ug/L 100 5) CHLOROMETHANE 4.98 50 238904 16.64 ug/L 100 6) VINYL CHLORIDE 5.14 62 284406 19.92 ug/L 94 7) BROMOMETHANE 6.05 94 190102 15.22 ug/L 99 8) CHLOROETHANE 6.17 64 136748 13.97 ug/L 99 9) TRICHLOROFLUOROMETHANE 6.70 101 399308 12.88 ug/L 98 10) ACETONE 7.64 43 41012 8.64 ug/L 95 11) 1,1-DICHLOROETHENE 7.98 61 411290 10.23 ug/L 96 12) METHYLENE CHLORIDE 8.95 49 423853 10.87 ug/L 94 13) METHYL TERT BUTYL ETHER 9.24 73 448262 8.71 ug/L 100 14) TRANS-1,2-DICHLOROETHENE 9.60 61 429708 9.85 ug/L 89 15) 1,1-DICHLOROETHANE 10.49 63 558964 10.28 ug/L 96 16) 2-BUTANONE (MEK) 11.30 43 67954 8.10 ug/L 94 17) 2,2-DICHLOROPROPANE 11.68 77 480806 10.73 ug/L 99 18) CIS-1,2-DICHLOROETHENE 11.78 96 303925 9.97 ug/L 85 19) CHLOROFORM 12.10 83 578542 11.15 ug/L 100 20) BROMOCHLOROMETHANE 12.48 49 259900 10.55 ug/L 90 21) 1,2-DICHLOROETHANE 13.81 62 363199 10.40 ug/L 99 24) 1,1,1-TRICHLOROETHANE 12.99 97 471404 10.68 ug/L 99 25) 1,1-DICHLOROPROPENE 13.31 75 432182 9.92 ug/L 98 26) CARBON TETRACHLORIDE 13.57 117 410335 10.93 ug/L 97 27) BENZENE 13.91 78 1208238 9.54 ug/L 97 28) TRICHLOROETHENE 15.17 95 326123 9.61 ug/L 96 29) 1,2-DICHLOROPROPANE 15.53 63 331924 9.41 ug/L 99 30) DIBROMOMETHANE 16.18 174 119270 9.50 ug/L 96 31) BROMODICHLOROMETHANE 16.02 83 428597 10.55 ug/L 100 32) 2-CHLOROETHYL VINYL ETHER 16.53 63 109262 8.34 ug/L 91 33) Methyl iso-butyl ketone 16.60 58 52606 7.81 ug/L 99 ------------------------------------------------------------------------- (#) = qualifier out of range (m) = manual integration 0103C10.D HP121001.M Thu Jan 03 09:58:46 2002 Page 1

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